I can't say I timed it. In the past I've heard a 100 hours. That being said it's not an on off kind of thing. Probably biggest change in first dozen hours. More subtle as time goes on. So I'll also say this. I've experienced it first hand on several pieces. Nobody yet has presented a plausible description to what is actually happening (being how they test fine before and after break in.
Also I don't remember having the same kind of experience with other kinds of film caps.
Some don't believe in cap break in at all.