I used to record on VHS Hi-Fi all the time. It was the best recorder I had for quite a while. I used to record music/DJ parties on VHS until I finally got a DAT machine. I've got 78 tapes of music, just from these parties, more tapes from other sources (mostly radio). But, I'll never do that again (record audio only on VHS Hi-Fi). Although at first glance it does sound quite good, the more you listen the more problems you hear. If you do record on VHS Hi-Fi, I suggest to only use the 2H mode. 6H mode has a hard time tracking, especially after some time has passed. Even in the 2H mode, switching noise (from switching between heads) is often times audible. I've found that with complex music, I rarely hear the head switching noise, but very simple/minimalist music allows me to notice it much more. And, since there are two different heads reading the track, they will most likely not be perfectly matched and have different performance. For example, I have one machine that has slightly greater high frequency noise in one head than the other. It is pretty easy to see which head is used at a particular point in time on the recording.
If you are interested, I've attached a few pictures of test tones I recorded onto a VHS tape almost 10 years before I made these measurements. This is a tape that was recorded in the 2H mode. This is a program that I am currently writing, so some things are missing, like proper vertical scales on the FFT display. Still, it is useful. The first picture is a full bandwidth picture of a 1kHz tone at nearly full scale (-2dB). Besides all the harmonic distortion (all the way up to the 17th harmonic), there is plenty of hash. All of this is a result of the head switching phenomena. Note the lowest significant spur at 30Hz (the switching rate). The next picture is a zoom of the 1kHz signal, with the marker on the next lower spur at 952Hz (the actual test signal is 982Hz) - exactly 30Hz lower. Just about all of these spikeys are IMD products of the 30Hz switching and 1kHz test tone. Just to be fair, I've included a picture of a 1kHz test tone at -10dB. Much less harmonic distortion, but the IM distortion is still there. The spike at the right end of the spectrum, around 15kHz, is the line frequency of video and is always there.