The better speaker cabinet stuffing material
The question was answered a long time ago. See the blog by Ken Kantor on this subject. The blog is somewhat technical. If you spend the time to digest it, it is easy to follow.
http://auralization.blogspot.com/?zx=a7750b35f5725eac
Fiberglass:
Fiberglass was the first material to achieve widespread commercial usage as a “stuffing” material for loudspeakers, specifically intended to increase the effective volume of a sealed enclosure. Already widely used to line the inside walls of speaker cabinets thanks to its excellent sound absorption and insulation properties, fiberglass was now distributed throughout the inside of sealed woofers to lower system resonance and improve bass response. This innovation is generally attributed to Villchur for use in his “Acoustic Research” products. The reduction of internal reflections and “standing waves” at higher frequencies was also present, and was considered an important collateral benefit.
Villchur tended to explain, (rather casually), that the fiberglass acts on Fc primarily through its thermal mass, continuously exhanging heat and pressure in the system, and thus altering the acoustics of the sealed box from “adiabatic to isothermal.” For example, an inward motion of the woofer, which decreases the size of the sealed cavity, results in a slighly lower than expected pressure. In effect, the box looks bigger that it is. Alternatively, but equivalently, he described the effect as a lowering of the speed of sound in the box.
It is easy to measure the empirical results of adding fiberglass to a sealed box. Fc is noticably reduced, and there is a downward effect on Qtc. It has long been a matter of debate as to what extent there are bona fide thermodynamic, cyclic heat exchange processes occuring in the box, as opposed to purely viscous damping of the air, flow resistance and tortuosity effects. It has been shown repeatedly and convincingly that the introduction of simple resistive damping to a closed box system will result in superficially similar effects on both Fc and Qtc. However, experimental evidence (here and elsewhere), suggests that fiberglass shows behavior that goes at least somewhat beyond pure resistive damping.
Synthetic Polymer Fibers:
Fiberglass is not an easy material to work with in a manufacturing environment. It requires the use of respirators and gloves, at a minimum, and is irritating to operators. The need to “fluff” the fiberglass from its sheet form into a shape appropriate for speaker filling exacerbates the problem. This has led loudspeaker manufacturers to seek alternatives of similar effectiveness, but with friendlier material properties. Dacron®, Hollofil® and similar polyester fibers in wad form have emerged as the leading candidates, and are now widely used.
It is important not to consider all types of synthetic fiber fill to be equivalently effective. There is a wide range of material available, from readily available types intended for making pillows, to hollow core fibers used for thermal insulation, to fibers of triadic cross-section specifically designed for audio use. Generally, the best of these have excellent midrange damping properties, but still fall somewhat short of fiberglass in their ability to lower Fc. This has not proven fatal to their commercial use, but it does present a problem for manufacturers attempting to implement a running change to an established design, and to hobbyists and repair shops engaged in restoration activities. It also demands of the engineer the ability to undertand and specify material properties in a domain that is often unfamiliar and poorly understood. This leads to sub-optimal “stuffing” in both professional and amateur loudspeaker designs.